SYNTHETIC FLUOROPHLOGOPITE CRYSTALS

(FLUORINE MICA, KMg3(AlSi3O10)F2)

The synthetic fluorine mica, fluorophlogopite KMg3(AlSi3O10)F2, contains no (OH)- of the natural phlogopite KMg3(AlSi3O10)(OH)2. The (OH)- is fully substituted with F- . Large fluorine mica crystals of high quality are grown by a Bridgman-Stockbarger method using platinum crucibles with seeds. The fluorine mica has the following unique characteristics : highly chemical stability, excellent transmittance, outgasing-free at high temperature in vacuum, excellent electrical insulation, high heat endurance (up to 1100 °C), non-radioactive background, highly flexible and cleavable, which are much superior to that of natural mica.

The synthetic mica sheets are suitable for a variety of uses such as substrates of thin film, windows and monochromater for x-ray, neutron diffraction, microwave and optics, spacers of electrical vacuum devices, supporters at high temperature and water-gauges of high pressure boilers, and etc., which are important in modern industry and most advanced branches of science.

Physical properties:

Heat endurance (°C) 1100

Melting temperature (°C) 1378

Density(g/cm3) 2.8

Dielectric strength (KV/mm) ~180

Volume resistivity ( W-cm) 4x1016

Surface resistivity ( W-cm) 3x1012

Dielectric constant (e) ~6

Dielectric loss (tgd) (1MH) 3x10-4

Tensile strength (Kg/cm2) ~1500

Optical indexes : Np=1.5239

Nm=1.5450

Ng=1.5470

Moisture absorption (%) none

Crystallographic data

Space group : C2/m

Lattice parameters : a=5.308(2) Å, b=9.183(3)Å and c=10.139(1)Å

b=100.07(2)